COMBINED CALORIMETRIC MODULE FOR INVESTIGATION OF THERMOPHYSICAL PROPERTIES OF COMPOSITE MATERIALS


  • V. V. Korskanov Institute of Macromolecular Chemistry of the National Academy of Sciences of Ukraine
  • Y. L. Karpova Institute of Macromolecular Chemistry of the National Academy of Sciences of Ukraine
  • N. V. Rukhailo Institute of Macromolecular Chemistry of the National Academy of Sciences of Ukraine
  • S. Y. Lobok Institute of Macromolecular Chemistry of the National Academy of Sciences of Ukraine
  • V. B. Dolhoshei Kiev National University of Architecture and Construction

Abstract

A design and principle of operation of the combined calorimeter module (CCM) for the integrated study of thermal properties of composite materials in a wide range of temperatures. Based on the results of using the CMC described thermodynamic properties of nanocomposites (NC) epoxy-based polymer and karbonanotrubok (CST). It has been shown that extreme changes in thermodynamic properties when the mass content of the CST in NC w = 0,3-0,4% are the result of samoasotsiatsii components and result in the formation of the polymer matrix in a continuous heat-conductive nanoparticle cluster of CST, which causes a sharp increase in the thermal conductivity and thermal diffusivity.

References

1. Wunderlich B. Thermal Analysis of Materials // Springer.– 2005. – 907 p.



2. McHugh J., Fideu P., Herrmann A., Stark W. Determination and review of specific heat capacity measurements during isothermal cure of an epoxy using TM-DSC and standard DSC techniques. Test method // Polymer testing. – 2010. – Vol. 29. – P. 759 - 765.



3. Spiropoulou E., Brown J., Pantazopoulos, G., Voulgaris D. Investigation of power failure of a heating device operated in a differential scanning calorimeter (DSC) // Engineering Failure Analysis. – 2015. – Vol. 55. – P. 360 - 369.



4. Drissi S., Eddhahak, A., Caré S., Neji J. Thermal analysis by DSC of Phase Change Materials, study of the damage effect // Journal of Building Engineering. – 2015. – Vol. 1. – P. 13 - 19.



5. Rathgeber Ch., Miró L. , Cabeza L.F., Hiebler S. Measurement of enthalpy curves of phase change materials via DSC and T-History: When are both methods needed to estimate the behaviour of the bulk material in applications? // Thermochimica Acta. –2014. – Vol. 596. – P. 79 - 88.



6. Waszkielis K.M., Białobrzewski I., Nowak K.W., Dzadz Ł., Dach J. Determination of the thermal conductivity of composted material // Measurement. – 2014. – Vol. 58. – P. 441 - 447.

7. Кэй Дж., Лэби Т. Таблицы физических и химических постоянных. М:.–1962. – 248 с.



8. Бернштейн В.А., Егоров В.М. Дифференциальная сканирующая калориметрия в физикохимии полимеров. – Л.: Химия, 1990. – 256 с.



9. Hu M., Yu D., Wei J. Thermal conductivity determination of small polymer samples by differential scanning calorimetry // Polymer Testing. – 2007. – Vol. 26. – P. 333 – 337.



10. Лемеш Н.В., Лысенков Э.А., Гомза Ю.П., Клепко В.В. и др. Структура многослойных углеродных нанотрубок, полученных каталитическим разложением этилена на наночастичах никеля. // Український хімічний журнал. – 2010. – Т. 76, №5. – С. 29 - 36.



11. Корсканов В.В. Термодинаміка формування та теплофізичні властивості нанокомпозитів на основі епоксидного полімеру та карбонанотрубок // Доповіді НАН України. – 2013. – №11. – С. 83 - 89.



12. Крамаренко В.Ю., Dudkin S.M., Alig I., Привалко В.П. Влияние функциональности мономеров на кинетику формирования и свойства алифатических полиизоциануратов // Высокомол. соед. – 2006. – Сер. А. – Т. 48, № 11. – С. 1957 - 1967.



13. Базаров И.П. Термодинамика. М.: Высшая школа, 1991. – 376 с.
Published
2016-03-31
How to Cite
Korskanov, V. V., Karpova, Y. L., Rukhailo, N. V., Lobok, S. Y., & Dolhoshei, V. B. (2016, March 31). COMBINED CALORIMETRIC MODULE FOR INVESTIGATION OF THERMOPHYSICAL PROPERTIES OF COMPOSITE MATERIALS. Ceramics: Science and Life, (3(32), 30-41. https://doi.org/10.26909/csl.3.2016.3